| Thursday 03 October 2019 | 1 | x | 2 |
| 16:50 | FC Astana vs FK Partizan | 1.05 | 2.25 | 3.00 | +70 |
| 18:55 | BSC Young Boys vs Rangers FC | 0.90 | 2.70 | 2.90 | +70 |
| 18:55 | CSKA Moscow vs RCD Espanyol Barcelona | 1.25 | 2.35 | 2.25 | +70 |
| 18:55 | AZ Alkmaar vs Manchester United | 3.25 | 2.60 | 0.85 | +71 |
| 18:55 | Besiktas vs Wolverhampton Wanderers | 1.55 | 2.30 | 1.80 | +70 |
| 18:55 | Wolfsberger AC vs Roma | 4.00 | 3.15 | 0.65 | +71 |
| 18:55 | AS Saint-Etienne vs Wolfsburg | 1.85 | 2.35 | 1.50 | +70 |
| 18:55 | FC Oleksandriya vs KAA Gent | 3.25 | 2.75 | 0.85 | +71 |
| 18:55 | Sporting Braga vs SK Slovan Bratislava | 0.45 | 3.55 | 6.25 | +70 |
| 18:55 | Basaksehir FK vs Borussia Monchengladbach | 1.75 | 2.40 | 1.55 | +71 |
| 18:55 | Ferencvarosi TC vs Ludogorets 1945 Razgrad | 1.75 | 2.25 | 1.65 | +70 |
| 18:55 | Feyenoord Rotterdam vs Porto | 2.00 | 2.35 | 1.40 | +70 |
| 21:00 | Celtic FC vs FC Cfr 1907 Cluj | 0.55 | 2.95 | 5.75 | +69 |
| 21:00 | Trabzonspor vs Basel | 1.40 | 2.30 | 2.05 | +70 |
| 21:00 | Malmo vs FC Copenhagen | 1.20 | 2.30 | 2.50 | +70 |
| 21:00 | FC Lugano vs FC Dynamo Kiev | 1.75 | 2.20 | 1.65 | +70 |
| 21:00 | Vitoria Guimaraes vs Eintracht Frankfurt | 3.65 | 2.55 | 0.80 | +70 |
| 21:00 | Sporting vs LASK | 0.70 | 2.85 | 4.00 | +70 |
| 21:00 | Rosenborg BK vs PSV Eindhoven | 3.50 | 2.55 | 0.85 | +70 |
| 21:00 | Sevilla vs Apoel Nicosia | 0.25 | 4.75 | 10.00 | +69 |
| 21:00 | Arsenal vs Standard Liege | 0.30 | 4.75 | 9.25 | +70 |
| 21:00 | Lazio vs FC Stade Rennes | 0.55 | 3.20 | 5.00 | +70 |
| 21:00 | F91 Dudelange vs Qarabag FK | 3.90 | 2.75 | 0.70 | +71 |
| 21:00 | FC Krasnodar vs Getafe | 1.65 | 2.10 | 1.85 | +70 |
